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- W2014609500 abstract "Hg(II)-mediated tandem Overman rearrangement and intramolecular amidomercuration reactions were proven to provide a convenient tool for the stereoselective synthesis of cis- and trans-2,6-disubstituted piperidines. Thus, upon treatment with Hg(OTFA)2 in THF, the trichloroacetimidate 1 directly transformed into the 2,6-dialkyl piperidine 2 with almost exclusive trans selectivity. The amiodomercuration reaction of the carbamate 7 by Hg(OTFA)2 in nitromethane showed an excellent cis selectivity. Also reported is the stereoselective synthesis of solenopsin A and isosolenopsin A." @default.
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- W2014609500 date "2004-07-31" @default.
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- W2014609500 title "Tandem Overman Rearrangement and Intramolecular Amidomercuration Reactions. Stereocontrolled Synthesis of <i>cis</i>- and <i>trans</i>-2,6-Dialkylpiperidines" @default.
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- W2014609500 doi "https://doi.org/10.1021/ol048961w" @default.
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