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- W2014617897 abstract "The extraction of dansyl-amino acid anions from an alkaline aqueous medium was studied by the use of dicationic anion-exchange extractants, polymethylenebis(trioctylphosphonium)s (abbreviated as CnBPs; n=2–12). As for the extraction of dianionic species, such as dansyl-aspartic acid anion (Dns-Asp2−) and dansyl-glutamic acid anion (Dns-Glu2−), the dicationic extractants were greatly superior to a monocationic extractant, butyltrioctylphosphonium (BuMP). However, regarding the extraction of monoanionic species, such as dansyl-serine anion, dansyl-phenylalanine anion, and dansyl-valine anion, the extraction abilities of the dicationic extractants and the monocationic extractant were similar to one another. The extraction ability of dicationic extractants was remarkably dependent on the length of their bridge-chain, which connects the two ionic centers. For extractants having short bridge-chain (C2BP–C4BP), Dns-Asp2− was more extracted than Dns-Glu2−. On the contrary, for extractants with long bridge-chain (C8BP–C12BP) , Dns-Glu2− was more extracted than Dns-Asp2−. The solvent effect on the extraction of Dns-Asp2− and Dns-Glu2− was also studied." @default.
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- W2014617897 date "1991-02-01" @default.
- W2014617897 modified "2023-09-27" @default.
- W2014617897 title "Solvent Extraction of Dansyl-Amino Acid Anions by Dicationic Extractants" @default.
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- W2014617897 doi "https://doi.org/10.1246/bcsj.64.476" @default.
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