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- W2014656543 abstract "We herein report on the different coordination behavior of phosphite–olefin ligands containing either a terminal olefin moiety or a related compound containing an internal olefin moiety to a CpCo(I)-center. While the former coordinates to the metal center via P atom and olefin moiety upon irradiation, photolysis of the latter led to the subsequent formation of the phosphorus-free [CpCo(η4-1,3-butadiene)] complex (6). A mechanistic rational of the decomposition reaction based on an Arbuzov-like rearrangement is suggested." @default.
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- W2014656543 date "2014-08-01" @default.
- W2014656543 modified "2023-09-27" @default.
- W2014656543 title "Decomposition mechanism of a cobalt-coordinated phosphite–olefin ligand under irradiation" @default.
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- W2014656543 doi "https://doi.org/10.1016/j.jorganchem.2014.04.013" @default.
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