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- W2014659507 abstract "Unusually large and sharp “adsorption waves” appear in cyclic voltammograms of Co(CN)53− and several cobalt(III) pentacyano complexes at stationary mercury electrodes. The nature of the adsorbed species and the reasons for the absence of the adsorption waves in polarograms taken with a DME have been examined. The data are compatible with the adsorption, in all cases, of a coordinatively unsaturated cobalt(II) complex, Co(CN)42−, by means of a cobalt-mercury bond. When the resulting adsorbed complex is reduced, a series of subsequent chemical and electrode reactions is initiated in which three faradays of charge are consumed for each mole of adsorbed complex. The adsorption of the anionic complex strongly retards the reduction of other negatively charged complexes." @default.
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- W2014659507 title "Electrochemical behavior of pentacyanocobaltate(II) and substituted pentacyanocobaltate(III) complexes at mercury electrodes" @default.
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- W2014659507 doi "https://doi.org/10.1016/s0022-0728(71)80161-4" @default.
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