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- W2014667145 abstract "Abstract Condensation of 2-acetamido-2-deoxy-5,6- O -isopropylidene- d -mannofuranose with disodium acetonedicarboxylate and subsequent esterification with diphenyldiazomethane yielded diphenylmethyl 6-acetamido-2,4,6-trideoxy- d - glycero -β- d - galacto -dec-3-ulopyranosonate ( 3 ), and its 5- and 6-epimer. Hydrogenation gave the corresponding free acids. Hydrogenation of ester 3 and working-up under alkaline conditions afforded stable ammonium 6-acetamido-2,4,6-trideoxy- d - glycero -β- d - galacto -dec-3-ulopyranosonate which, on heating, led to an anomeric mixture of 5-acetamido-1,3,5-trideoxy- d - glycero - d - galacto -non-2-ulopyranose." @default.
- W2014667145 created "2016-06-24" @default.
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- W2014667145 date "1992-12-01" @default.
- W2014667145 modified "2023-09-26" @default.
- W2014667145 title "Synthesis of the deculopyranosonic acid analog of N-acetylneuraminic acid, its 5-epimer and 6-epimer, and of 5-acetamido-1,3,5-trideoxy-d-glycero-d-galactonon-2-ulopyranose" @default.
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- W2014667145 doi "https://doi.org/10.1016/0008-6215(92)85008-n" @default.
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