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- W2014668891 abstract "Abstract The Raman spectra of Guanosine-5′-Monophosphate (GMP) in aqueous solution and in the presence of a variety of metals have been obtained and analysed. The metalGMP interactions and associations have been studied quantitatively from intensity measurements of several vibrational bands of GMP. The interactions of base pairing and base staking of GMP molecules in the presence and absence of metal ions are modified as it is indicated from the intensity measurement of the characteristic base or phosphate bands of the mono nucleotide. It was found that the relative intensities of the guanine base bands at 1488, 1366, 1323 and 672 cm−1 changed in the order Pt > Hg > Ni > Co > Mn > Mg > Ca in freshly studied aqueous solutions of GMP in the presence of the chloride salts of the above metals. In addition, the relative intensity of the phosphodiester bond (OPO) and the PO2−3 at 810 and 978 cm−1 respectively do change in the presence of the above metal chlorides indicating conformational changes about the phosphodiester bond and some interaction with the PO2−3 phosphate end of th molecule with most of the metals as a function of metal concentration in solution." @default.
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- W2014668891 title "Raman study of metalguanosine-5′-monophosphate aqueous solutions" @default.
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- W2014668891 doi "https://doi.org/10.1016/s0020-1693(00)84201-2" @default.
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