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• W2014679204 endingPage "3969" @default.
• W2014679204 startingPage "3962" @default.
• W2014679204 abstract "Abstract The ion–molecule reactions of dimethyl ether with cyclometalated [Pt(bipy−H)] + were investigated in gas‐phase experiments, complemented by DFT methods, and compared with the previously reported ion–molecule reactions with its sulfur analogue. The initial step corresponds in both cases to a platinum‐mediated transfer of a hydrogen atom from the ether to the (bipy−H) ligand, and three‐membered oxygen‐ and sulfur‐containing metallacycles serve as key intermediates. Oxidative CC bond coupling (“dehydrosulfurization”), which dominates the gas‐phase ion chemistry of the [Pt(bipy−H)] + ion with dimethyl sulfide, is practically absent for dimethyl ether. The competition in the formation of C 2 H 4 and CH 2 X (X=O, S) in the reactions of [Pt(bipy−H)] + with (CH 3 ) 2 X (X=O, S) as well as the extensive H/D exchange observed in the [Pt(bipy−H)] + /(CH 3 ) 2 O system are explained in terms of the corresponding potential‐energy surfaces." @default.
• W2014679204 created "2016-06-24" @default.
• W2014679204 creator A5031367654 @default.
• W2014679204 creator A5039008448 @default.
• W2014679204 creator A5059088310 @default.
• W2014679204 date "2010-03-26" @default.
• W2014679204 modified "2023-10-18" @default.
• W2014679204 title "Ion-Molecule Reactions of “Rollover” Cyclometalated [Pt(bipy−H)]+ (bipy=2,2′-bipyridine) with Dimethyl Ether in Comparison with Dimethyl Sulfide: An Experimental/Computational Study" @default.
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• W2014679204 doi "https://doi.org/10.1002/chem.200902742" @default.
• W2014679204 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20186911" @default.
• W2014679204 hasPublicationYear "2010" @default.

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