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• W2014680863 endingPage "6115" @default.
• W2014680863 startingPage "6107" @default.
• W2014680863 abstract "ETS-4 is a titanium silicate developed by Engelhard Corporation, which possesses a small pore network, the size of which can be reduced by heat treatment to improve its kinetic selectivity in nitrogen/methane separation. Most of the reported studies about ETS-4 employ crystals synthesized with conventional heating. Furthermore, information available on the adsorption properties of ETS-4, especially the diffusion properties, is scarce. In this work, Na-ETS-4 crystals have been synthesized by microwave heating and have been exchanged with strontium to obtain Sr-ETS-4 using also microwave heating. This method for obtaining the strontium form of ETS-4 has not been reported before. Both materials have been dehydrated to reduce their pore size. The adsorption and diffusion parameters of nitrogen and methane on these materials, which have not been measured for microwave-synthesized ETS-4 up to the present date, have been estimated by modeling the desorption breakthrough curves of both gases using a fixed bed of ETS-4 crystals. The kinetic selectivity of nitrogen over methane at 298 K of microwave-synthesized Sr-ETS-4 is 26. This value is higher than the maxima reported in the literature for this material." @default.
• W2014680863 created "2016-06-24" @default.
• W2014680863 creator A5007819525 @default.
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• W2014680863 date "2008-05-17" @default.
• W2014680863 modified "2023-10-17" @default.
• W2014680863 title "Adsorption and Diffusion Parameters of Methane and Nitrogen on Microwave-Synthesized ETS-4" @default.
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• W2014680863 doi "https://doi.org/10.1021/la7037894" @default.
• W2014680863 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18484754" @default.
• W2014680863 hasPublicationYear "2008" @default.
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