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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2014689586> ?p ?o ?g. }

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• W2014689586 abstract "The first Rh(I)-catalyzed addition of alkenylboron reagents to imines is described. The Rh(I)-catalyzed addition of potassium alkenyltrifluoroborate salts to both aromatic and aliphatic N-tert-butanesulfinyl aldimines proceeds in good yields (up to 97%) and with very high diastereoselectivities (95:5 to >99:1). This new method enables the general and efficient asymmetric synthesis of the important class of alpha-branched allylic amines from readily available and stable starting materials." @default.
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• W2014689586 date "2009-03-03" @default.
• W2014689586 modified "2023-10-04" @default.
• W2014689586 title "Asymmetric Synthesis of α-Branched Allylic Amines by the Rh(I)-Catalyzed Addition of Alkenyltrifluoroborates to <i>N</i>-<i>tert</i>-Butanesulfinyl Aldimines" @default.
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• W2014689586 doi "https://doi.org/10.1021/ja9002603" @default.
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