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• W2014712887 abstract "Thermodynamic parameters such as free energy, enthalpy and entropy of transfer from the bulk aqueous phase to the air-water interface at 25°C for 41 hydrophobic compounds of environmental interest are calculated from literature data on adsorption. The compounds considered are neutral, non-polar or slightly polar in nature. They comprise aliphatic hydrocarbons, halocarbons, formates, esters, branched alkanes, alcohols, acids and aromatic hydrocarbons and halocarbons. The trends in values among various homologous series of compounds are ascertained. A simple adsorption model based on interfacial energy changes predicts the values satisfactorily; however, the prediction is sensitive to the orientation of the molecule at the air-water interface. The free energy changes are linearly related to other water to solvent (octanol) partition constants. The significance of air-water interfacial adsorption parameters in high surface area environmental systems is discussed with special relevance to several important examples." @default.
• W2014712887 created "2016-06-24" @default.
• W2014712887 creator A5084503964 @default.
• W2014712887 date "1994-04-01" @default.
• W2014712887 modified "2023-09-27" @default.
• W2014712887 title "Hydrophobic compounds in the environment: Adsorption equilibrium at the air-water interface" @default.
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• W2014712887 doi "https://doi.org/10.1016/0043-1354(94)90088-4" @default.
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