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- W2014713098 abstract "A thermodynamic model of the ϕ/ϕ class of methods that can be easily used with commercial process simulators is proposed. The vapor−liquid equilibrium (VLE) is calculated by means of a Redlich−Kwong-type equation of state (EoS) that uses modified Huron−Vidal mixing rules with activity coefficients: the activity coefficients are derived from the NRTL model whose parameters are evaluated by fitting VLE data of binary mixtures. By means of the Aspen PLUS process simulator, a comparison is made between the performances of both the proposed method with user-created adaptive parameters that can be forced into the simulator database and the Predictive−Soave−Redlich−Kwong (PSRK) method that uses UNIFAC to compute the excess free energy. The ethanol−water separation by extractive distillation is analyzed to point out how an incorrect prediction of the azeotrope can lead to underestimation of the overall process energy requirement." @default.
- W2014713098 created "2016-06-24" @default.
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- W2014713098 date "2010-04-12" @default.
- W2014713098 modified "2023-10-17" @default.
- W2014713098 title "Using an Adaptive Parameter Method for Process Simulation of Nonideal Systems" @default.
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- W2014713098 doi "https://doi.org/10.1021/ie901773q" @default.
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