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- W2014713171 abstract "Addition of tri(2-furyl)phosphine, PFu 3 , to [Os 3 (CO) 10 (μ-H) 2 ] at room temperature gives [HOs 3 (CO) 10 (PFu 3 )(μ-H)] ( 1 ), while in refluxing toluene the same reactants afford [Os 3 (CO) 9 {μ 3 -PFu 2 (C 4 H 2 O)}(μ-H)] ( 2 ) resulting from orthometallatation of a furyl ring. Reaction of PFu 3 with [Os 3 (CO) 10− n (NCMe) n ] ( n = 0, 1, 2) affords the substituted clusters [Os 3 (CO) 12− n (PFu 3 ) n ] ( n = 1–3) ( 3–5 ), the phosphine ligands occupying equatorial position in all cases. Heating [Os 3 (CO) 11 (PFu 3 )] ( 3 ) in refluxing octane gives [Os 3 (CO) 9 (μ 3 -PFu)(μ 3 -η 2 -C 4 H 2 O)] ( 6 ) which results from both carbon–hydrogen and carbon–phosphorus bond activation and contains both μ 3 -η 2 -furyne and furylphosphinidene ligands. All new clusters have been characterized by spectroscopic methods together with single crystal X-ray diffraction for 2 , 3 and 6 . The reactivity of tri(2-furyl)phosphine (PFu 3 ) with triosmium clusters has been investigated. Both carbon–hydrogen and carbon–phosphorus bond activation products have been isolated together with simple substitution products. ► carbon-hydrogen bond activation of trifurylphosphine. ► synthesis of triosmium furyne complex. ► generation of furylphosphinidene ligand." @default.
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- W2014713171 date "2011-01-01" @default.
- W2014713171 modified "2023-09-24" @default.
- W2014713171 title "Reaction of tri(2-furyl)phosphine with triosmium clusters: C–H and P–C activation to afford furyne and phosphinidene ligands" @default.
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- W2014713171 doi "https://doi.org/10.1016/j.jorganchem.2010.09.046" @default.
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