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- W2014713323 abstract "Abstract The kinetics of CO substitution in Cr(CO)6 to afford Cr(CO)5PPh3 in the presence of different alkyl amine N-oxides, R3NO, and aryl amine N-oxides (p-X-C6H4)(CH3)2NO, are reported. Within each type of amine N-oxide. the rates of reaction increase with increasing basicity of the amine N-oxide. However, even at lower basicities, the aryl reagents react more rapidly than do the alkyl reagents. Competition experiments between py (pyridine) and P(n-Bu) for the coordinatively unsaturated intermediates “M(CO)5” show that the discrimination abilities increase in the order Cr" @default.
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- W2014713323 date "1991-01-01" @default.
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- W2014713323 title "Effect of substituents on amineN-oxides on the rates of O-atom transfer to metal carbonyls" @default.
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- W2014713323 doi "https://doi.org/10.1016/0022-328x(91)86227-h" @default.
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