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• W2014713384 endingPage "11291" @default.
• W2014713384 startingPage "11285" @default.
• W2014713384 abstract "The dissociation dynamics of energy selected i-C(3)H(7)X (X = H, Cl, Br, and I) ions have been investigated by imaging photoelectron-photoion coincidence (iPEPICO) spectroscopy using synchrotron radiation from the X04DB VUV beamline in the Swiss Light Source of the Paul Scherrer Institut. The 0 K dissociation energy (E(0)) for i-C(3)H(8) was determined to be 11.624 ± 0.002 eV. This leads to a 298 K isopropyl ion heat of formation of 805.9 ± 0.5 kJ mol(-1). The Δ(f)H(298K)°(i-C(3)H(7)(+)) combined with the measured 0 K onsets for i-C(3)H(7)(+) formation from isopropyl chloride (11.065 ± 0.004 eV), isopropyl bromide (10.454 ± 0.008 eV), and isopropyl iodide (9.812 ± 0.008 eV) yields the 298 K isopropyl chloride, bromide, and iodide heats of formation of -145.7 ± 0.7, -95.6 ± 0.9, and -38.5 ± 0.9 kJ mol(-1), respectively. These values provide a significant correction to literature values and reduce the error limits. Finally, the new i-C(3)H(7)(+) heat of formation leads to a predicted adiabatic ionization energy for the isopropyl radical of 7.430 ± 0.012 eV and a 298 K proton affinity for propene of 744.1 ± 0.8 kJ mol(-1)." @default.
• W2014713384 created "2016-06-24" @default.
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• W2014713384 creator A5005819552 @default.
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• W2014713384 date "2010-07-09" @default.
• W2014713384 modified "2023-10-16" @default.
• W2014713384 title "Dissociation Dynamics of Energy Selected, Propane, and <i>i-</i>C₃H₇X⁺ Ions by iPEPICO: Accurate Heats of Formation of <i>i</i>-C₃H₇⁺, <i>i</i>-C₃H₇Cl, <i>i</i>-C₃H₇Br, and <i>i</i>-C₃H₇I" @default.
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• W2014713384 doi "https://doi.org/10.1021/jp104200h" @default.
• W2014713384 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20617794" @default.
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