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- W2014717574 abstract "An efficient, high-yielding strategy has been developed for the asymmetric total synthesis of seven norditerpenoid dilactones known for their diverse biological properties. The three key steps employed to obtain a tricyclic lactone intermediate involved a Morita−Baylis−Hillman reaction, the stereocontrolled construction of a γ-lactone through bromolactonization, and an efficient catalytic Reformatsky-type reaction. Access to CJ-14,445, LL-Z1271γ, oidiolactones A, B, C, and D, and nagilactone F was possible from a common intermediate. Structures and stereochemistry were determined by X-ray analysis." @default.
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- W2014717574 date "2009-09-24" @default.
- W2014717574 modified "2023-10-11" @default.
- W2014717574 title "Total Synthesis of Oidiodendrolides and Related Norditerpene Dilactones from a Common Precursor: Metabolites CJ-14,445, LL-Z1271γ, Oidiolactones A, B, C, and D, and Nagilactone F" @default.
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- W2014717574 doi "https://doi.org/10.1021/ol901896c" @default.
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