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• W2014717757 endingPage "8218" @default.
• W2014717757 startingPage "8210" @default.
• W2014717757 abstract "Structural, electronic, and optical properties of the thiolate-protected Au(38)(SR)(24) cluster are studied by density-functional theory computations (R = CH(3) and R = C(6)H(13)) and by powder X-ray crystallography (R = C(12)H(25)). A low-energy structure which can be written as Au(23)@(Au(SR)(2))(3)(Au(2)(SR)(3))(6) having a bi-icosahedral core and a chiral arrangement of the protecting gold-thiolate Au(x)(SR)(y) units yields an excellent match between the computed (for R = C(6)H(13)) and measured (for R = C(12)H(25)) powder X-ray diffraction function. We interpret in detail the electronic structure of the Au(23) core by using a particle-in-a-cylinder model. Although the alkane thiolate ligands are achiral, the chiral structure of the ligand layer yields strong circular dichroism (CD) in the excitations below 2.2 eV for Au(38)(SCH(3))(24). Our calculated CD spectrum is in quantitative agreement with the previously measured low-energy CD signal of glutathione-protected Au(38)(SG)(24). Our study demonstrates a new mechanism for the strong chiral response of thiolate-protected gold clusters with achiral metal cores and ligands." @default.
• W2014717757 created "2016-06-24" @default.
• W2014717757 creator A5011230883 @default.
• W2014717757 creator A5020046323 @default.
• W2014717757 creator A5020126853 @default.
• W2014717757 creator A5021542072 @default.
• W2014717757 creator A5032181533 @default.
• W2014717757 date "2010-05-25" @default.
• W2014717757 modified "2023-10-11" @default.
• W2014717757 title "Chirality and Electronic Structure of the Thiolate-Protected Au₃₈ Nanocluster" @default.
• W2014717757 cites W1529850994 @default.
• W2014717757 cites W179471644 @default.
• W2014717757 cites W1969327376 @default.
• W2014717757 cites W1973912200 @default.
• W2014717757 cites W1973961500 @default.
• W2014717757 cites W1975320379 @default.
• W2014717757 cites W1976639056 @default.
• W2014717757 cites W1977035587 @default.
• W2014717757 cites W1978214538 @default.
• W2014717757 cites W1978290607 @default.
• W2014717757 cites W1979232921 @default.
• W2014717757 cites W1980807995 @default.
• W2014717757 cites W1981368803 @default.
• W2014717757 cites W1982059494 @default.
• W2014717757 cites W1984191478 @default.
• W2014717757 cites W1984379455 @default.
• W2014717757 cites W1984431504 @default.
• W2014717757 cites W1988659705 @default.
• W2014717757 cites W1989855030 @default.
• W2014717757 cites W1991691934 @default.
• W2014717757 cites W1992083269 @default.
• W2014717757 cites W1996155296 @default.
• W2014717757 cites W1997236222 @default.
• W2014717757 cites W1998096575 @default.
• W2014717757 cites W2000935529 @default.
• W2014717757 cites W2003031243 @default.
• W2014717757 cites W2004370951 @default.
• W2014717757 cites W2010710144 @default.
• W2014717757 cites W2012401131 @default.
• W2014717757 cites W2012860474 @default.
• W2014717757 cites W2023559789 @default.
• W2014717757 cites W2028178195 @default.
• W2014717757 cites W2029510139 @default.
• W2014717757 cites W2031304228 @default.
• W2014717757 cites W2032362534 @default.
• W2014717757 cites W2033096857 @default.
• W2014717757 cites W2035126461 @default.
• W2014717757 cites W2035280024 @default.
• W2014717757 cites W2035946616 @default.
• W2014717757 cites W2036255100 @default.
• W2014717757 cites W2037244776 @default.
• W2014717757 cites W2041036661 @default.
• W2014717757 cites W2042994860 @default.
• W2014717757 cites W2048917513 @default.
• W2014717757 cites W2050307916 @default.
• W2014717757 cites W2054273170 @default.
• W2014717757 cites W2056319595 @default.
• W2014717757 cites W2056467312 @default.
• W2014717757 cites W2058702870 @default.
• W2014717757 cites W2058760502 @default.
• W2014717757 cites W2059427804 @default.
• W2014717757 cites W2060653029 @default.
• W2014717757 cites W2060906968 @default.
• W2014717757 cites W2062470136 @default.
• W2014717757 cites W2064106802 @default.
• W2014717757 cites W2066175031 @default.
• W2014717757 cites W2066286007 @default.
• W2014717757 cites W2067049138 @default.
• W2014717757 cites W2069807403 @default.
• W2014717757 cites W2073839928 @default.
• W2014717757 cites W2076641907 @default.
• W2014717757 cites W2077228161 @default.
• W2014717757 cites W2077635436 @default.
• W2014717757 cites W2080376276 @default.
• W2014717757 cites W2081409618 @default.
• W2014717757 cites W2082468665 @default.
• W2014717757 cites W2085210149 @default.
• W2014717757 cites W2086265161 @default.
• W2014717757 cites W2091265465 @default.
• W2014717757 cites W2091582826 @default.
• W2014717757 cites W2094135064 @default.
• W2014717757 cites W2094361366 @default.
• W2014717757 cites W2094839583 @default.
• W2014717757 cites W2095374362 @default.
• W2014717757 cites W2095459615 @default.
• W2014717757 cites W2096868202 @default.
• W2014717757 cites W2108299472 @default.
• W2014717757 cites W2129569338 @default.
• W2014717757 cites W2132629607 @default.
• W2014717757 cites W2140537016 @default.
• W2014717757 cites W2141686621 @default.
• W2014717757 cites W2145413612 @default.
• W2014717757 cites W2150345533 @default.
• W2014717757 cites W2164325425 @default.
• W2014717757 cites W2170370859 @default.
• W2014717757 cites W2323331435 @default.
• W2014717757 cites W2325824199 @default.
• W2014717757 cites W2329132121 @default.

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