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- W2014718148 abstract "The influences of molecular, crystalline and granular structures on the biodegradability of compression-molded starch films were investigated. Fungal α-amylase was used as model degradation agent. The substrates comprised varied starch structures obtained by different degrees of acid hydrolysis, different granular sizes using size fractionation, and different degrees of crystallinity by aging for different times (up to 14 days). Two stages are identified for unretrograded films by fitting degradation data using first-order kinetics. Starch films containing larger molecules were degraded faster, but the rate coefficient was independent of the granule size. Retrograded films were degraded much slower than unretrograded ones, with a similar rate coefficient to that in the second stage of unretrograded films. Although initially the smaller molecules or the easily accessible starch chains on the amorphous film surface were degraded faster, the more ordered structure (resistant starch) formed from retrogradation, either before or during enzymatic degradation, strongly inhibits film biodegradation." @default.
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- W2014718148 date "2015-05-01" @default.
- W2014718148 modified "2023-10-07" @default.
- W2014718148 title "Biodegradation of starch films: The roles of molecular and crystalline structure" @default.
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- W2014718148 doi "https://doi.org/10.1016/j.carbpol.2015.01.011" @default.
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