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- W2014721079 abstract "Seventeen new catalyst precursors for the syndiospecific polymerization of propylene are presented. The new metallocene complexes are substituted in the positions 2 and 7 of the fluorenylidene fragment by MeO-, halogen-, alkyl- and aryl groups. The focus is directed on effective new synthetic routes to substituted fluorenes and the preparation of the catalyst precursors. In addition first polymerization results are reported. Siebzehn neue Metallocen-Katalysatorvorstufen für die syndiospezifische Polymerisation von Propylen mit MeO-, Halogen-, Alkyl- und Arylsubstituenten in den Positionen 2 und 7 des Fluorenylidenfragmentes werden vorgestellt. Im Mittelpunkt stehen effektive neue Synthesewege für die Darstellung substituierter Fluorene und die Synthese der Katalysatorvorstufen; darüber hinaus wird über erste Polymerisationsergebnisse berichtet." @default.
- W2014721079 created "2016-06-24" @default.
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- W2014721079 date "1996-09-01" @default.
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- W2014721079 title "Syndiospezifische polymerisation von propylen: 2- und 2,7-substituierte metallocenkomplex des typs (C13H8−nRnCR′2C5H4)MCl2 (n = 1,2; R alkoxy, alkyl, aryl, hal; R′ Me, Ph; M Zr, Hf)" @default.
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- W2014721079 doi "https://doi.org/10.1016/0022-328x(95)06045-x" @default.
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