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- W2014728611 abstract "The role of co-ordinated BH2 and BH3 groups as proton acceptors in hydrogen bonding has been studied by examining complexes between phenol, as an example of a proton donor, and the co-ordinated boranes Me3N·BH2X (XH, Cl, Br and I), py·BH3 and Et3P·BH3. Some complexes of p-fluorophenol and t-butanol have also been examined. The enthalpies of formation have been determined by measuring the absorbance of the free-OH stretching band in the infrared over a range of temperature. The values of -ΔH fall in the range 1·7–3·5 kcal/mol. For phenol as the proton donor, the strengths of hydrogen bonds formed by Me3N·BH2X decrease in the order H > Cl > Br > I." @default.
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- W2014728611 date "1974-05-01" @default.
- W2014728611 modified "2023-09-25" @default.
- W2014728611 title "Hydrogen bonds between co-ordinated BH3 and BH2 groups and OH groups. Thermodynamics of formation by infrared spectroscopy" @default.
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- W2014728611 doi "https://doi.org/10.1016/0584-8539(74)80028-0" @default.
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