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- W2014731686 abstract "Abstract The meso and rac forms of the tetraphosphine ligand bis[(diphenylphosphinoethyl)phenylphosphino]methane, Ph2PCH2CH2PPhCH2PPhCH2CH2PPh2 (DPPEPM), have been separated and found to react with 2 equiv of [PtCl2(cod)] or [PtMe2(cod)] to generate bimetallic complexes of the form [Pt2X4(μ-DPPEPM)]. When [PtClMe(cod)] is treated with the tetraphosphine followed by TlPF6, the chloride-bridged species [Pt2Me2(μ-Cl)(μ-DPPEPM)]PF6 is obtained. The solid state structures of [Pt2X4(μ-meso-DPPEPM)] (X=Cl, Me) are reported, along with preliminary studies of some hydrogenation reactions catalyzed by the bimetallic derivatives." @default.
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- W2014731686 date "2002-09-01" @default.
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- W2014731686 title "Bimetallic platinum complexes containing linear tetraphosphine ligands" @default.
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- W2014731686 doi "https://doi.org/10.1016/s1387-7003(02)00516-6" @default.
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