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- W2014733394 abstract "13C nuclear magnetic resonance spectra were obtained for methyl esters oferythro- andthreo-9,10-dihydroxystearates, for 12-hydroxy-cis- andtrans-9-octadecenoates, and forthreo-12,13-dihydroxy-cis-andtrans-9-octadecenoates.Erythro andthreo compounds may be distinguished easily by the difference in the chemical shifts of the carbons alpha to the hydroxy-bearing carbons. Monohydroxy compounds are easily distinguished fromvicinal dihydroxy compounds by differences in chemical shifts of both the hydroxy-bearing carbons and of the carbons alpha to them. The presence of a hydroxy-bearing carbon beta to a double bond results in the two carbons of the double bond of a hydroxy-bearing carbon beta to a double bond results in the two carbons of the double bond having different chemical shifts, with the numerical values being different for thecis andtrans isomers. The chemical shift of a carbon alpha to both a doubly bonded carbon and a hydroxy-bearing carbon is influenced both by the geometry of the double bond and the number of hydroxy-bearing carbons." @default.
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- W2014733394 date "1979-01-01" @default.
- W2014733394 modified "2023-09-27" @default.
- W2014733394 title "13C nuclear magnetic resonance of mono-and dihydroxy saturated and unsaturated fatty methyl esters" @default.
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- W2014733394 doi "https://doi.org/10.1007/bf02533573" @default.
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