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- W2014737845 abstract "Todorokite of chemical composition (Mg0.77Na0.03)(Mg0.18Mn2+0.60Mn4+5.22) O12 ⋅ 3.07 H2O was synthesized by a two-step procedure. First, sodium birnessite was synthesized and magnesium was exchanged for sodium to form magnesium birnessite, which was autoclaved under a saturated steam pressure at 155°C for 8 hours to form well-crystallized todorokite. Synthesized todorokite particles consisted of fibers extending from a central plate. The plate itself was made of twinned fibers forming a trilling pattern. The infrared spectra and x-ray diffraction patterns were similar to those of natural todorokite samples. Calcium birnessite and nickel birnessite, when autoclaved under conditions similar to those for magnesium birnessite, yielded a todorokite structure. However, the formation of todorokite from calcium and nickel birnessite was less extensive." @default.
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- W2014737845 date "1986-02-14" @default.
- W2014737845 modified "2023-10-01" @default.
- W2014737845 title "Synthesis of Todorokite" @default.
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- W2014737845 doi "https://doi.org/10.1126/science.231.4739.717" @default.
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