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- W2014739076 endingPage "2694" @default.
- W2014739076 startingPage "2689" @default.
- W2014739076 abstract "The ω-technique of Wheland and Mann was introduced into the graph theory of aromaticity in order to improve the resonance energies of nonalternant hydrocarbons. For these compounds, the ω-technique resonance energy was more or less smaller than the resonance energy calculated on the basis of the simplest Hückel MO model. Especially, several compounds thus far considered to be aromatic were predicted to be substantially olefinic with much reduced resonance energies. They are calicene, sesquifulvalene, azulene, dibenzo[cd,gh]pentalene, and cyclohepta[def]fluorene. Many aspects of their chemistry were evidently consonant with the improved resonance energies. Possible limitation of the use of electrophilic substitution as a criterion of aromaticity was discussed. Resonance energies of alternant hydrocarbons are not modified by application of the ω-technique." @default.
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- W2014739076 date "1980-10-01" @default.
- W2014739076 modified "2023-10-18" @default.
- W2014739076 title "Improved Resonance Energies of Nonalternant Hydrocarbons. An ω-Technique Approach" @default.
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- W2014739076 doi "https://doi.org/10.1246/bcsj.53.2689" @default.
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