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• W2014744239 abstract "The pressure-composition isotherms and electrochemical characteristics of titanium-based hydrogen storage alloys have been studied for various compositions. In the TiZrVMnNi system, Ti0.2Zr0.05V0.4Mn0.35 − xNix (x = 0.1–0.25) alloys were found to have a large hydrogen storage capacity (greater than 1.75 wt.% g−1 alloy) and high discharge capacity (350–440 mA h g−1). Their structure was confirmed to be multi-phase and composed of an AB2-type C14 Laves phase matrix and V-rich b.c.c. second phase by using X-ray diffraction, scanning electron microscope and electron microprobe analyses. In order to identify the contribution of each phase to the high discharge capacity of multi-phase alloys, these two phases were prepared separately and their hydrogen storage capacities were investigated. It was found that the V-rich b.c.c. second phase was hardly hydrogenated in KOH electrolyte, though its theoretical hydrogen storage capacity was as high as 1.93 wt.% H g−1 alloy as determined from the pressure-composition isotherms in the solid-gas reaction. Its potential hydrogen storage capacity was able to be utilized by the presence of a C14 matrix phase which had a catalytic activity for the charge-transfer reaction in KOH electrolyte." @default.
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• W2014744239 date "1996-05-01" @default.
• W2014744239 modified "2023-09-23" @default.
• W2014744239 title "The Ti-based metal hydride electrode for NiMH rechargeable batteries" @default.
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• W2014744239 doi "https://doi.org/10.1016/0925-8388(96)02276-1" @default.
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