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• W2014749668 endingPage "1805" @default.
• W2014749668 startingPage "1795" @default.
• W2014749668 abstract "Abstract The coordination chemistry of the DPPA‐type functional phosphine bis(diphenylphosphino)( N ‐thioether)amine N(PPh 2 ) 2 (CH 2 ) 3 SMe ( 1 ) and its monosulfide derivative, (Ph 2 P)N{P(S)Ph 2 }(CH 2 ) 3 SMe ( 1⋅S ), towards Ni II precursors has been investigated. The crystal structures of N{P(S)Ph 2 } 2 (CH 2 ) 3 SMe ( 1⋅S 2 ), [NiCl 2 {(Ph 2 P) 2 N(CH 2 ) 3 SMe‐ P,P }] ( 2 ), [NiCl 2 ((Ph 2 P)N{P(S)Ph 2 }(CH 2 ) 3 SMe‐ P,S )] ( 3 ), [Ni((Ph 2 P)N{P(S)Ph 2 }(CH 2 ) 3 SMe‐ P,S ) 2 ]NiCl 4 ( 3′ ), [Ni((Ph 2 P)N{P(S)Ph 2 }(CH 2 ) 3 SMe‐ P,S ) 2 ](BF 4 ) 2 ( 4 ), and [Ni((Ph 2 P)NH{P(S)Ph 2 }‐ P,S ) 2 ]Cl 2 ( 5 ) have been determined by single‐crystal X‐ray diffraction. In all of the complexes with the hybrid ligand 1⋅S , P,S‐chelation to the Ni II center is observed. Despite the stability generally associated with five‐membered ring chelation, easy migration of this LL′‐type P,S‐chelating ligand from one metal center to another was observed, which accounts for the reversible ligand‐redistribution reaction occurring in the equilibrium between the neutral, diamagnetic complex [NiCl 2 LL′] and the paramagnetic ion‐pair [Ni(LL′) 2 ][NiCl 4 ]. Detailed investigations by multinuclear NMR, UV/Vis, and FTIR spectroscopic methods and DFT calculations are reported. Each of the formula isomers 3 and 3′ can be selectively obtained, depending on the experimental conditions." @default.
• W2014749668 created "2016-06-24" @default.
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• W2014749668 date "2013-06-21" @default.
• W2014749668 modified "2023-10-18" @default.
• W2014749668 title "Solvent-Dependent Reversible Ligand Exchange in Nickel Complexes of a Monosulfide Bis(diphenylphosphino)(<i>N</i>-thioether)amine" @default.
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• W2014749668 doi "https://doi.org/10.1002/asia.201300687" @default.
• W2014749668 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23794386" @default.
• W2014749668 hasPublicationYear "2013" @default.
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