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- W2014751799 abstract "A new color center based on a local structural and chemical change of the average borate tungstate glass matrix has been identified. The matrices of the colored glasses all had a 1:1 ratio of Li2B4O7 and WO3 except for glasses with x = 0. The reaction took place in air and at 1200 K in all cases, while the reaction time varied between 10 and 60 min. Subsequent to reaction, the glasses were cooled to 550 K in 1 min and then annealed in air at that temperature for 2 h. The coloration starts at a critical temperature Tc = 630 K and needs latent sites. The coloration process involves a distribution of energy barriers for the migration of Li+ with half-width comparable to its mean value, 2.91 eV. The achieved center concentrations are estimated to lie between 0.3 and 3 mol%. In addition, a color center has been found which is connected with Fe+3 impurities. This coloration is reversible and connected with a temperature-induced shift, 5 × 10−4 eV/K, of the Fe-based oscillators." @default.
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- W2014751799 date "1996-01-01" @default.
- W2014751799 modified "2023-10-16" @default.
- W2014751799 title "New thermally induced color centers in lithium borate tungstate glasses, (Li2B4O7)100 − x(WO3)x" @default.
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- W2014751799 doi "https://doi.org/10.1016/0022-3093(95)00460-2" @default.
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