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- W2014754906 abstract "Rotational analysis of the (0,0) band of the B2Σ-X2Σ transition of ScS is reported. Spectrographic illustration of a hyperfine coupling transition in the ground state is demonstrated for the first time. This enables an order of magnitude to be obtained for γ″ (∼0.003 cm−1). The results for the other constants were: X state: B″ = 0.1971 cm−1, D″ = 5 × 10−8cm−1, 4b = 0.23 cm−1 (equal to that for ScO within the limits of measurement uncertainty); B state: B′ = 0.1853 cm−1, D′ = 6 × 10−8cm−1, γ′ = −0.0594 cm−1, which can be compared with pA2Π = 0.060 cm−1. It was found that the two excited states A2Π and B2Σ constitute an excellent example of pure precession (ppp = 0.058 cm−1, and this enables the vibrational levels of A2Π to be numbered. On a effectué l'étude rotationnelle de la bande (0,0) de la transition B2Σ-X2Σ de ScS. Pour la première fois est décelée en graphie une transition de couplage dans l'état fondamental ce qui permet d'obtenir un ordre de grandeur de γ″ (∼0.003 cm−1). Pour les autres constantes on a obtenu: état X: B″ = 0.1971 cm−1, D″ = 5 × 10−8cm−1, 4b = 0.23 cm−1 (égale à celle de ScO aux incertitudes de mesure près); état B: B′ = 0.1853 cm−1, D′ = 6 × 10−8cm−1, γ′ = −0.0594 cm−1, que l'on compare à pA2Π = 0.060 cm−1. On vérifie que les deux états excités A2Π et B2Σ constituent un excellent exemple de pure précession (ppp = 0.058 cm−1), ce qui permet de numéroter les niveaux de vibration de A2Π." @default.
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- W2014754906 date "1979-10-01" @default.
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- W2014754906 title "Rotational study and hyperfine effects of the (0,0) band of the B2Σ-X2Σ system of ScS" @default.
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- W2014754906 doi "https://doi.org/10.1016/0022-2852(79)90034-1" @default.
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