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- W2014755933 abstract "A 1D complex [{[Cu2([12]aneN3)2(p-paa)(H2O)2](ClO4)2}[Cu2([12]aneN3)2(p-paa)2]] n ([12]aneN3 = 1,5,9-triazacyclododecane, p-paa = p-benzenebicarboxylate) has been synthesized and structurally characterized. The complex contains two different binuclear copper(II) moieties. One part includes a binuclear copper(II) unit and non-coordinated perchlorate anions. A neutral binuclear copper(II) part which forms a zigzag chain structure via the bridging p-paa ligand completes the unit-cell. Elemental analysis, IR, UV-Vis spectra and magnetic properties for the complex have also been determined. Magnetic susceptibilities in the solid state are measured over the temperature range from 77 to 300 K, showing a weak antiferromagnetic coupling with a best fit J 1 = −3.09 cm−1, J 2 = −5.279 cm−1, g = 2.099 and R = 1.226 × 10−5." @default.
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- W2014755933 date "2008-03-03" @default.
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- W2014755933 title "Synthesis, crystal structure and properties of a 1D copper(II) complex with 1,5,9-triazacyclododecane bridged by p -benzenebicarboxylate" @default.
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- W2014755933 doi "https://doi.org/10.1080/00958970701371359" @default.
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