FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2014757662> ?p ?o ?g. }

• W2014757662 endingPage "5983" @default.
• W2014757662 startingPage "5977" @default.
• W2014757662 abstract "A novel and convenient route to the first poly(ferrocenylsilanes) with alkoxy and aryloxy substituents at silicon is reported. The reaction sequence involves (i) unexpectedly facile and clean halogen replacement at the bridging atom of a readily accessible dichlorosilyl-bridged [1]ferrocenophane Fe(η-C5H4)2SiCl2 (3) by OR groups via reactions with aliphatic alcohols and phenols in the presence of an HCl acceptor and (ii) thermal or transition metal-catalyzed ring-opening polymerization of the new [1]ferrocenophanes of structure Fe(η-C5H4)2Si(OR)2 (4). This allows the preparation of high molecular weight poly(ferrocenylsilanes) [Fe(η-C5H4)2Si(OR)2]n with side group substituents such as short chain alkoxy groups (5a−5b, R = OMe, OEt), fluorinated ethoxy groups (5c, R = OCH2CF3), long chain alkoxy groups (5d−5g, R = OBu, OHex, OC12H25, OC18H37), and aryloxy substituents (5h, 5i, and 5k, R = OPh, OPh-p-tBu, OPh-p-tBu, OPh-p-Ph) at silicon. The molecular structures of the [1]ferrocenophane monomers 4a and 4j have been studied by single-crystal X-ray diffraction, and these species possess strained structures with tilt angles between the planes of the cyclopentadienyl ligands of 18−19°. The new poly(ferrocenylsilanes) possess a wide range of glass transition temperatures (Tg = −51° (5e) to 97 °C (5k)) and the materials with long chain (OC12 (5f) or OC18 (5g)) alkoxy groups crystallize and exhibit melt transitions (Tm) at −30 and +32 °C, respectively. Wide-angle X-ray scattering studies of 5g suggest a lamellar structure with interdigitated side groups. Cyclic voltammetry studies of the selected poly(ferrocenylsilanes) 5a and 5i show the characteristic two-wave pattern for poly(ferrocenes) with interacting iron atoms with a redox coupling ΔE = ca. 0.22 V." @default.
• W2014757662 created "2016-06-24" @default.
• W2014757662 creator A5019368956 @default.
• W2014757662 creator A5029332574 @default.
• W2014757662 creator A5032926098 @default.
• W2014757662 creator A5035086516 @default.
• W2014757662 creator A5066197128 @default.
• W2014757662 creator A5076582889 @default.
• W2014757662 creator A5081001172 @default.
• W2014757662 date "1998-08-19" @default.
• W2014757662 modified "2023-10-14" @default.
• W2014757662 title "Synthesis, Characterization, and Properties of Symmetrically Substituted, Ring-Opened Poly(ferrocenylalkoxy/aryloxysilanes)" @default.
• W2014757662 cites W1965459878 @default.
• W2014757662 cites W1970511600 @default.
• W2014757662 cites W1979170136 @default.
• W2014757662 cites W1980493019 @default.
• W2014757662 cites W1999877353 @default.
• W2014757662 cites W2005240576 @default.
• W2014757662 cites W2013023551 @default.
• W2014757662 cites W2019048766 @default.
• W2014757662 cites W2022886366 @default.
• W2014757662 cites W2023352881 @default.
• W2014757662 cites W2030674375 @default.
• W2014757662 cites W2037269142 @default.
• W2014757662 cites W2038482300 @default.
• W2014757662 cites W2046501755 @default.
• W2014757662 cites W2052388369 @default.
• W2014757662 cites W2060153092 @default.
• W2014757662 cites W2065635211 @default.
• W2014757662 cites W2068277961 @default.
• W2014757662 cites W2075442635 @default.
• W2014757662 cites W2080731876 @default.
• W2014757662 cites W2084558115 @default.
• W2014757662 cites W2132009441 @default.
• W2014757662 cites W2907273550 @default.
• W2014757662 cites W4233121406 @default.
• W2014757662 doi "https://doi.org/10.1021/ma980275n" @default.
• W2014757662 hasPublicationYear "1998" @default.
• W2014757662 type Work @default.
• W2014757662 sameAs 2014757662 @default.
• W2014757662 citedByCount "38" @default.
• W2014757662 countsByYear W20147576622012 @default.
• W2014757662 countsByYear W20147576622013 @default.
• W2014757662 countsByYear W20147576622015 @default.
• W2014757662 countsByYear W20147576622016 @default.
• W2014757662 countsByYear W20147576622022 @default.
• W2014757662 crossrefType "journal-article" @default.
• W2014757662 hasAuthorship W2014757662A5019368956 @default.
• W2014757662 hasAuthorship W2014757662A5029332574 @default.
• W2014757662 hasAuthorship W2014757662A5032926098 @default.
• W2014757662 hasAuthorship W2014757662A5035086516 @default.
• W2014757662 hasAuthorship W2014757662A5066197128 @default.
• W2014757662 hasAuthorship W2014757662A5076582889 @default.
• W2014757662 hasAuthorship W2014757662A5081001172 @default.
• W2014757662 hasConcept C115624301 @default.
• W2014757662 hasConcept C121332964 @default.
• W2014757662 hasConcept C166940927 @default.
• W2014757662 hasConcept C178790620 @default.
• W2014757662 hasConcept C185592680 @default.
• W2014757662 hasConcept C188027245 @default.
• W2014757662 hasConcept C203897987 @default.
• W2014757662 hasConcept C204921945 @default.
• W2014757662 hasConcept C26873012 @default.
• W2014757662 hasConcept C2779892579 @default.
• W2014757662 hasConcept C2780263894 @default.
• W2014757662 hasConcept C2780378348 @default.
• W2014757662 hasConcept C44228677 @default.
• W2014757662 hasConcept C521977710 @default.
• W2014757662 hasConcept C71240020 @default.
• W2014757662 hasConcept C8010536 @default.
• W2014757662 hasConcept C90150868 @default.
• W2014757662 hasConceptScore W2014757662C115624301 @default.
• W2014757662 hasConceptScore W2014757662C121332964 @default.
• W2014757662 hasConceptScore W2014757662C166940927 @default.
• W2014757662 hasConceptScore W2014757662C178790620 @default.
• W2014757662 hasConceptScore W2014757662C185592680 @default.
• W2014757662 hasConceptScore W2014757662C188027245 @default.
• W2014757662 hasConceptScore W2014757662C203897987 @default.
• W2014757662 hasConceptScore W2014757662C204921945 @default.
• W2014757662 hasConceptScore W2014757662C26873012 @default.
• W2014757662 hasConceptScore W2014757662C2779892579 @default.
• W2014757662 hasConceptScore W2014757662C2780263894 @default.
• W2014757662 hasConceptScore W2014757662C2780378348 @default.
• W2014757662 hasConceptScore W2014757662C44228677 @default.
• W2014757662 hasConceptScore W2014757662C521977710 @default.
• W2014757662 hasConceptScore W2014757662C71240020 @default.
• W2014757662 hasConceptScore W2014757662C8010536 @default.
• W2014757662 hasConceptScore W2014757662C90150868 @default.
• W2014757662 hasIssue "18" @default.
• W2014757662 hasLocation W20147576621 @default.
• W2014757662 hasOpenAccess W2014757662 @default.
• W2014757662 hasPrimaryLocation W20147576621 @default.
• W2014757662 hasRelatedWork W1985502457 @default.
• W2014757662 hasRelatedWork W1985543175 @default.
• W2014757662 hasRelatedWork W2009532072 @default.
• W2014757662 hasRelatedWork W2033732154 @default.
• W2014757662 hasRelatedWork W2046532721 @default.
• W2014757662 hasRelatedWork W2126839885 @default.

• next