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- W2014760286 abstract "Abstract IR spectra of the species GeHD 2 CH 2 F and GeHD 2 CH 2 Cl are reported which show two bands each, assigned to the solitary GeH bond either gauche or trans to the halogen atom, the splittings being 17 cm −1 (F) and 25.5 cm −1 (Cl), respectively. Similar pairs of bands are identified as due to GeHD 2 CH 2 Br, SiHD 2 CH 2 Cl and SiHD 2 CH 2 Br in earlier spectra. This conformational effect of halogen on ν(SiH) or ν(GeH) accounts for the doublets seen earlier in the spectra of R 2 MHCH 2 Cl and R 2 MHCHCl 2 compounds by Egorochkin et al. and alternatively attributed by them to “free”, and “intramolecularly bonded” germanium of the type ." @default.
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- W2014760286 date "1982-03-01" @default.
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- W2014760286 title "SiH and GeH stretching frequency variations in rotational conformers of MHCH2X compounds" @default.
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- W2014760286 doi "https://doi.org/10.1016/s0022-328x(00)83413-0" @default.
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