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- W2014760710 abstract "In 1935, Wigner and Huntington (WH) predicted that at a density D Met=0.62 mole H/cm3, ‘very low temperatures’, and a pressure greater than 25 GPa, body-centered cubic H2 would undergo an isostructural phase transition directly to H with an associated insulator-metal transition (IMT). WH also predicted an H2 structure type that might occur if the simple H2/H dissociative IMT does not exist: ‘It is possible … that a layer-like lattice … is obtainable under high pressure’. In 1991, Ashcroft predicted that the ‘geometric and dynamic nature of the (H–H) pairing’, possibly in a layered graphite-like structure, would substantially impede achieving metallic H2. In 1996, metallic fluid H was made under dynamic compression at 0.64 mole H/cm3, 140 GPa and T/T F≪1, where T F is Fermi temperature. In 2012, a layer-like lattice, called Phase IV, was discovered above ∼220 GPa static pressure. Phase IV is insulating and possibly semi-metallic up to ∼360 GPa, above which it has been predicted to become metallic. This paper is a historical perspective – a comparison of WH's predictions with recent dynamic, static and theoretical high pressure results. WH did extremely well." @default.
- W2014760710 created "2016-06-24" @default.
- W2014760710 creator A5010691442 @default.
- W2014760710 date "2013-06-01" @default.
- W2014760710 modified "2023-09-24" @default.
- W2014760710 title "Wigner and Huntington: the long quest for metallic hydrogen" @default.
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- W2014760710 doi "https://doi.org/10.1080/08957959.2013.784907" @default.
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