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- W2014772164 abstract "The development of the organocatalytic asymmetric one-pot Michael−Darzens condensation giving highly functionalized complex epoxycyclohexanone derivatives with up to four chiral centers is presented. Depending on the reaction conditions, either the polysubstituted 7-oxa-bicyclo[4.1.0]heptan-2-one ring system or 2-chloro-cyclohex-2-enone derivatives can be formed. For the former class of compounds a high diversity in substitution pattern is demonstrated, and the optically active products are obtained in excellent diastereo- and enantioselectivities. The potential synthetic applications of the products have been demonstrated by performing a series of highly diastereoselective transformations leading to optically active products useful for the life-science industry. Furthermore, mechanistic investigations on the formation of the chiral centers in the optically active epoxycyclohexanone are presented." @default.
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- W2014772164 date "2006-04-01" @default.
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- W2014772164 title "One-Pot Organocatalytic Domino Michael-Aldol and Intramolecular S<sub>N</sub>2 Reactions. Asymmetric Synthesis of Highly Functionalized Epoxycyclohexanone Derivatives" @default.
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- W2014772164 doi "https://doi.org/10.1021/ja058490o" @default.
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