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- W2014777103 abstract "The temperature effect on the single and double hydrogen atom transfer reactions in o-, m- and p-toluic acid n-butyl esters and isobutyl esters has been investigated. For the meta and para isomers, the abundance of the m/z 137 ion [C8H9O2]+ generated by a double hydrogen atom transfer reaction increases relative to the m/z 136 ion [C8H8O2]+˙ generated by a single hydrogen atom transfer reaction upon lowering the temperature of the ionization chamber. On the other hand, the ratio of the peak abundances [137]+/[136]+ for the ortho isomers is nearly constant when the temperature is changed. It is shown that this is due to the difference between the appearance energies of the m/z 136 and m/z 137 ions." @default.
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- W2014777103 date "1980-12-01" @default.
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- W2014777103 title "Temperature effect on the single and double hydrogen atom transfer reactions ino-, m-andp-toluic acid butyl esters" @default.
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- W2014777103 doi "https://doi.org/10.1002/oms.1210151204" @default.
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