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- W2014782606 abstract "The structure and protein resistance of oligo(ethylene glycol)-terminated self-assembled monolayers (OEG-SAMs) have been studied intensively using various techniques. However, their molecular-scale surface structures have not been well understood. In this study, we performed molecular-resolution imaging of OH-terminated SAMs (OH-SAMs) and hexa(ethylene glycol) SAMs (EG(6)OH-SAMs) formed on a Au(111) surface in an aqueous solution by frequency modulation atomic force microscopy (FM-AFM). The results show that most of the ethylene glycol (EG) chains in an EG(6)OH-SAM are closely packed and well-ordered to present a molecularly flat surface even in an aqueous solution. In addition, we found that EG(6)OH-SAMs have nanoscale defects, where molecules take a disordered arrangement with their molecular axes parallel to the substrate surface. We also found that the domain size (50-200 nm) of an EG(6)OH-SAM is much larger than that of OH-SAMs (10-40 nm). These findings should significantly advance molecular-scale understanding about the surface structure of OEG-SAMs." @default.
- W2014782606 created "2016-06-24" @default.
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- W2014782606 date "2014-07-10" @default.
- W2014782606 modified "2023-10-16" @default.
- W2014782606 title "Molecular-scale surface structures of oligo(ethylene glycol)-terminated self-assembled monolayers investigated by frequency modulation atomic force microscopy in aqueous solution" @default.
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- W2014782606 doi "https://doi.org/10.1088/0957-4484/25/30/305602" @default.
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