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- W2014799557 abstract "A concentration cell using an ion-exchange semipermeable membrane as a septum for the measurement of the activities of ionic surfactants has been constructed, the method of measurement is here in described. The membranes used proved each to be exclusively permeable to one ion. The activities of both the tetradecyl sulfate ion (TS−) and the counterion (Na+) were determined. In the concentration region from 4.0×10−4 mol/1 to CMC, logf±=−(0.070logC+0.283) held for the mean activity coefficient, f±. The f± value at the CMC was found to be 0.81, considerably smaller than the value, 0.978, calculated by the Debye-Huckel equation taking account of the ionic size, 5.5 A. Above the CMC the activity of the TS− ion decreased, that of the Na+ ion increased, and the mean activity slightly increased with the NaTS concentration. The Gibbs adsorption isotherm was applied for the adsorption of NaTS, using exclusively the observed data of the amount of adsorption, the surface tension, and the activities. A satisfactory agr..." @default.
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- W2014799557 date "1975-10-01" @default.
- W2014799557 modified "2023-09-25" @default.
- W2014799557 title "Activity Measurement and Colloid Chemical Studies of Aqueous Sodium Tetradecyl Sulfate Solutions" @default.
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- W2014799557 doi "https://doi.org/10.1246/bcsj.48.2755" @default.
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