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- W2014844178 abstract "The effects of the temperature, initial concentration, and chemical quenchers on dual photoreactions of phthalazine were investigated. The results give further supporting evidence for a previously proposed reaction mechanism, i.e., phthalazine in the lowest excited singlet and triplet states affords singlet and triplet radical pairs, respectively, in the initial hydrogen abstraction process from 2-propanol. The singlet radical pair gives a reduction product in a solvent cage, whereas the radicals produced in the triplet state escape from the solvent cage, causing dimerization. On the basis of the reaction mechanism of dual photoreactions, external heavy-atom effects on the radical pairs within a solvent cage have been studied. The results indicate that heavy-atom perturbations bring about an enhancement of the intersystem crossing efficiency from the triplet-state radical pair to the singlet one, including a spin inversion of the radical pair in the solvent cage, rather than S1→T1 intersystem crossing induced within a single molecule of phthalazine." @default.
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- W2014844178 date "1991-11-01" @default.
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- W2014844178 title "Intersystem Crossing of Radical Pair in Solvent Cage. External Heavy Atom Effect on Dual Photoreactions of Phthalazine" @default.
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- W2014844178 doi "https://doi.org/10.1246/bcsj.64.3340" @default.
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