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- W2014847678 abstract "In this paper, a method for the generation of alkoxyamidyl radicals is presented. These N-centered radicals can efficiently be formed starting from the corresponding acylated alkoxyamines using IBX as an oxidant. Stereoselective 5-exo and 6-exo reactions with these N-heteroatom-centered radicals leading to isoxazolidines and [1,2]oxazinanes are discussed. The N−O bond in the heterocycles can readily be cleaved with SmI2 to provide N-acylated 1,3-amino alcohols." @default.
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- W2014847678 date "2005-07-22" @default.
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- W2014847678 title "Stereoselective Cyclization Reactions of IBX-Generated Alkoxyamidyl Radicals" @default.
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- W2014847678 doi "https://doi.org/10.1021/jo0509399" @default.
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