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- W2014849355 abstract "Diorganobis(1-pyrazolyl) borate methylplatinum(II) complexes of the type (R2Bpz2)PtMeL (R = C2H5 or C6H4, pz = 1-pyrazolyl and L = tertiary phosphine, isocyanide or acetylene) have been prepared. Stable acetylene complexes containing C6H5CCC6H5 and C6H5CCCH3 are obtained which are inert towards insertion of the acetylene into the PtCH3 bond. On the other hand, dimethylacetylene dicarboxylate and hexafluorobut-2-yne do not give analogous complexes but give directly the platinum(methylvinylic) insertion products. Spectroscopic data and bonding are discussed for neutral four- and five-coordinate methylplatinum(II) acetylene complexes." @default.
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- W2014849355 date "1975-11-01" @default.
- W2014849355 modified "2023-09-26" @default.
- W2014849355 title "cis-π-acetylenic methylplatinum(II) complexes" @default.
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- W2014849355 doi "https://doi.org/10.1016/s0022-328x(00)92477-x" @default.
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