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- W2014862860 abstract "A chiral non-aqueous CE system with UV and mass spectrometric detection has been developed. The enantioseparation was promoted by diastereomeric complex (ion-pair) formation between the amines (e.g. salbutamol, atenolol) and the chiral selector, (-)-2,3:4,6-di-O-isopropylidene-2-keto-L-gulonic acid [(-)-DIKGA]. Different solvent mixtures were studied, as well as different concentrations of (-)-DIKGA and ammonium acetate in the background electrolyte. A partial filling technique was developed with a selector plug composed of (-)-DIKGA and ammonium acetate in a solvent mixture of methanol and 2-propanol. The separated enantiomers of pronethalol were detected by a Q-TOF MS system equipped with a sheath-flow electrospray ionization interface." @default.
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- W2014862860 date "2003-01-01" @default.
- W2014862860 modified "2023-10-17" @default.
- W2014862860 title "Development of a chiral non-aqueous capillary electrophoretic system using the partial filling technique with UV and mass spectrometric detection" @default.
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- W2014862860 doi "https://doi.org/10.1016/s0021-9673(02)01866-6" @default.
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