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• W2014870767 abstract "The energy levels of the Nd3+ ion in Nd(C2H5SO4)3·9H2O and of the Er3+ ion in Er(C2H5SO4)3·9H2O are calculated within the 4fN configuration by the tensor operator method. The Hamiltonian containing a configuration interaction is diagonalized for the free ion levels and complete J-mixing is performed for the crystal field levels. The experimental “free-ion” energy levels of Nd3+ and Er3+ are fitted with a mean deviation of 70.8 cm−1 for 19 terms and 78.2 cm−1 for 22 terms, respectively. The crystal field parameters obtained for Nd(C2H5SO4)3·9H2O and Er(C2H5SO4)3·9H2O yield a mean deviation of 3.6 cm−1 for 43 levels and 3.6 cm−1 for 50 levels, respectively. The calculated Zeeman splitting factors (g values) in the direction along the crystal principal axis are in fair agreement with the experimental values." @default.
• W2014870767 created "2016-06-24" @default.
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• W2014870767 date "1977-04-01" @default.
• W2014870767 modified "2023-10-18" @default.
• W2014870767 title "Crystal Field Levels of Neodymium and Erbium Ethylsulfate Nonahydrates" @default.
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• W2014870767 doi "https://doi.org/10.1246/bcsj.50.862" @default.
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