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• W2014874826 abstract "Iron(II) complexes of a bidentate, a hexadentate and a series of tridentate ligands have been prepared and characterized. Electrochemical properties have shown that of the tridentate ligands, those capable of dπ-pπ bonding between the pyridyl rings and central ligand atom can stabilize formal low oxidation states (I,O, −I) of the metal. A bidentate ligand, 2-(2-pyridyl) imidazole although resembling 2,2′-bipyridine in structure, does not stabilize any low oxidation states and its iron(II) complex is reduced irreversibly to iron(O). The iron(II) complex of a hexadentate ligand, tetra(2-picolyl)ethylenediamine, is reduced in two, one electron steps to yield formal Fe(I) and Fe(O) oxidation states. However, both of these reductions are totally irreversible at a Pt and HMDE electrode." @default.
• W2014874826 created "2016-06-24" @default.
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• W2014874826 date "1981-01-01" @default.
• W2014874826 modified "2023-10-18" @default.
• W2014874826 title "Synthesis and electrochemical investigation of a series of iron(II) complexes with bidentate, tridentate and hexadentate ligands" @default.
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• W2014874826 doi "https://doi.org/10.1016/0022-1902(81)80154-6" @default.
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