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- W2014885191 abstract "Abstract Two three-dimensional frameworks composed of doubly interpenetrating networks of the same topology but different stereoisomeric structures have been constructed from self-assembly of the chiral building block, Δ- or Δ-[Nd(ntb)2]3+, with different spacers bipy and bpen (ntb = tris(2-benzimidazolylmethyl) amine, bipy = 4,4″-bipyridyl, bpen = trans-1,2-bis (4-pyridyl)ethylene). In the crystal structure of [Nd(ntb)2](ClO4)3·3bipy·2H2O the spacer bipy connects [Nd(ntb)2]3+ cations of the same handedness to generate a chiral network Δ3-Δ…(or Δ3-Δ…){[Nd(ntb)2](bipy)3}3+∞, which is interpenetrated further by another identical network. The crystal structure of [Nd(ntb)2](ClO4)3·3bpen·H2O shows a topologically similar but achiral framework in which non-planar and planar bpen spacers connect cations of the same chirality and a pair of enantiomers, respectively, thus generating a three-dimensional racemate Δ2Δ…(or Δ2Δ-Δ…){[Nd(ntb)2](bpen)3}3+∞. Aggregation of the molecular species is effected by N-H…N hydrogen bonds, and the observed enantioselective self-assembly can be rationalized by π…π interactions between aromatic rings." @default.
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- W2014885191 date "2001-01-01" @default.
- W2014885191 modified "2023-09-27" @default.
- W2014885191 title "Stereoisomeric Doubly Interpenetrating Three-Dimensional Networks of Tripodal Neodymium(III) Complexes from Spacer-Controlled Enantioselective Self-Assembly" @default.
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- W2014885191 doi "https://doi.org/10.1080/10610270108027473" @default.
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