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- W2014924192 abstract "The optical absorption spectra of Pr3+ and Nd3+ in single crystals of PbCl2 have been studied in the spectral region 10 000 to 29 000 cm−1 at liquid-nitrogen and liquid-helium temperatures. The crystal-field splitting is interpreted in terms of crystal field potentials of symmetry Cs. For PbCl2:Nd3+ the parameters B, B, B, B, B, B, B, B, and B have been determined from the positions of 20 Stark components. The RMS deviation of the fit was I cm−1. For PbCl2:Pr3+ the parameters B, B, B, B, and B were determined from 13 Stark components. The RMS deviation was 6 cm−1. (The parameters B are interpreted in terms of crystal field theory). These crystal field parameters are compared with those obtained earlier from EPR studies. Die Absorptionsspektren von Pr3+ und Nd3+ in Einkristallen von PbCl2 werden im Bereich von etwa 10 000 bis 29 000 cm−1 bei den Temperaturen von flüssigem Stickstoff und flüssigem Helium untersucht. Die Aufspaltungen der Terme der Nd3+- und Pr3+- Ionen werden mit einem Kristallfeldpotential der Symmetrie Cs interpretiert. Für PbCl2:Nd3+ werden die Parameter B, B, B, B, B, B, B, B und B von 20 beobachteten Kristallfeldkomponenten berechnet. Die mittlere Abweichung zwischen den gemessenen und mit diesen Parameterwerten berechneten Aufspaltungen beträgt I cm−1. Für PbCl2:Pr3+ werden die Parameter B, B, B, B und B von 13 beobachteten Komponenten berechnet. Die mittlere Abweichung beträgt 6 cm−1. Die Parameter wurden mit der Kristallfeld-theorie interpetiert und mit früheren EPR-Untersuchungen verglichen." @default.
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- W2014924192 date "1972-12-16" @default.
- W2014924192 modified "2023-09-26" @default.
- W2014924192 title "Optical absorption spectra and crystal-field calculations of Pr3+ and Nd3+ in PbCl2" @default.
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- W2014924192 doi "https://doi.org/10.1002/pssa.2210140224" @default.
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