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• W2014941251 abstract "Mechanochemistry is becoming increasingly popular amongst both the academic and industrial communities as an alternative method for inducing physical and chemical reactions. Despite its rapidly expanding application, little is understood of its mechanisms, greatly limiting its capacity. In the present work the application of specialty devices allowed submission of the simple organic system, α-glycine + β-malonic acid, to isolated shearing and impact treatment. In doing so, unique products were observed to result from each of these major mechanical actions; shear inducing formation of the known salt, glycinium semi-malonate (GSM), and impact yielding formation of a novel phase. Correlation of these isolated treatments with a more common ball mill indicated two unique regions within the milling jar, each characterised by varying ratios of shear and impact, leading to different products being observed. It is widely accepted that, particularly when considering organic systems, mechanical treatment often acts by inducing increases in local temperature, leading to volatilisation or melting. A combination of DSC and TGA were used to investigate the role of temperature on the system in question. Invariably, heating induced formation of GSM, with evidence supporting a eutectic melt, rather than a gas-phase reaction. Shear heating alone is unable to describe formation of the novel phase obtained through impact treatment. By considering the formation and character of mechanically produced tablets, a model is described that may account for formation of this novel phase. This system and methodology for mechanochemical study offers intriguing opportunities for continued study of this widely used and exciting field." @default.
• W2014941251 created "2016-06-24" @default.
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• W2014941251 date "2014-01-01" @default.
• W2014941251 modified "2023-10-05" @default.
• W2014941251 title "Advances in elucidating mechanochemical complexities via implementation of a simple organic system" @default.
• W2014941251 cites W1967266344 @default.
• W2014941251 cites W1968371747 @default.
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• W2014941251 cites W1979941456 @default.
• W2014941251 cites W1980565126 @default.
• W2014941251 cites W1981356530 @default.
• W2014941251 cites W1981468779 @default.
• W2014941251 cites W1983662791 @default.
• W2014941251 cites W1995846423 @default.
• W2014941251 cites W1997651593 @default.
• W2014941251 cites W2002317986 @default.
• W2014941251 cites W2003935519 @default.
• W2014941251 cites W2004458045 @default.
• W2014941251 cites W2004951578 @default.
• W2014941251 cites W2005158618 @default.
• W2014941251 cites W2006320900 @default.
• W2014941251 cites W2008689029 @default.
• W2014941251 cites W2011893890 @default.
• W2014941251 cites W2018159313 @default.
• W2014941251 cites W2024465183 @default.
• W2014941251 cites W2024583333 @default.
• W2014941251 cites W2025008573 @default.
• W2014941251 cites W2025155883 @default.
• W2014941251 cites W2025268557 @default.
• W2014941251 cites W2028559919 @default.
• W2014941251 cites W2029665772 @default.
• W2014941251 cites W2034631384 @default.
• W2014941251 cites W2039462623 @default.
• W2014941251 cites W2042783240 @default.
• W2014941251 cites W2048252175 @default.
• W2014941251 cites W2051740199 @default.
• W2014941251 cites W2052872403 @default.
• W2014941251 cites W2054534734 @default.
• W2014941251 cites W2057479065 @default.
• W2014941251 cites W2057605129 @default.
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• W2014941251 cites W2076204428 @default.
• W2014941251 cites W2080937409 @default.
• W2014941251 cites W2083148479 @default.
• W2014941251 cites W2083732877 @default.
• W2014941251 cites W2084850905 @default.
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• W2014941251 doi "https://doi.org/10.1039/c3fd00150d" @default.
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