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• W2014944562 abstract "We report high-pressure Raman measurements up to 20.2 GPa on the perovskite-type oxide (Na1/2Bi1/2)0.89Ba0.11TiO3 (NBT–BT0.11), which is of interest as a potential lead-free piezoelectric material. Distinct changes of the Raman spectra with increasing pressure illustrate that NBT–BT0.11 shows at least two phase transitions. First, the application of low pressure progressively reduces the tetragonal signature in NBT–BT0.11 and leads at around 1.8 GPa to a Raman spectrum reminiscent of rhombohedral NBT. Second, with further increase of pressure, the pressure-dependent behaviour of NBT–BT0.11 resembles that of NBT and transforms to a non-cubic high-pressure structure at around 9 GPa. These observations suggest that a progressive substitution of Na+/Bi3+ by Ba2+ pushes the pressure-induced structural instabilities of NBT towards higher pressure, corresponding to a Ba2+-induced negative (tensile) pressure within the structure." @default.
• W2014944562 created "2016-06-24" @default.
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• W2014944562 date "2005-09-30" @default.
• W2014944562 modified "2023-10-06" @default.
• W2014944562 title "The high-pressure behaviour of Ba-doped Na_1/2Bi_1/2TiO₃investigated by Raman spectroscopy" @default.
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• W2014944562 doi "https://doi.org/10.1088/0953-8984/17/41/027" @default.
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