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- W2014947082 abstract "Mo(CO)6 is adsorbed between the layers of aluminium pillared montmorillonite clay. The chemistry of interaction with the clay resembles that with zeolite HY; the carbonyl complex interacts with the structural hydroxyl groups of the clay, and can be decarbonylated partially and reversibly at 373 K and completely and irreversibly at 473 K. Complete decarbonylation is accompanied by oxidation of the molybdenum to the 5 + state. The method allows preparation of pillared clays containing about 1 wt.% transition metal. Similar chemistry occurs with Fe(CO)5." @default.
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- W2014947082 date "1992-07-01" @default.
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- W2014947082 title "Carbonyl complexes in pillared clays" @default.
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- W2014947082 doi "https://doi.org/10.1016/0304-5102(92)80246-d" @default.
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