Matches in SemOpenAlex for { <https://semopenalex.org/work/W2014961111> ?p ?o ?g. }
- W2014961111 endingPage "30" @default.
- W2014961111 startingPage "15" @default.
- W2014961111 abstract "Abstract Anisotropic double exchange interaction is considered for the valence-delocalized [Fe2.5+Fe2.5+] cluster with strong Anderson–Hasegawa double exchange (DE) coupling. The combined effect of spin–orbit interaction and DE between the excited states of the mixed-valence Fe ions results in the inter-ion anisotropic DE coupling. The coefficients of anisotropic DE coupling are linearly proportional to the parameters B0 and Bμ of the DE interaction in the ground and excited cluster states. The anisotropic DE interaction operates between the cluster states of different localizations of the extra electron. The anisotropic DE coupling results in the zero-field splitting (ZFS) of the valence-delocalized ground state of the [Fe2.5+Fe2.5+] cluster. The ZFS of the anisotropic DE origin is specific for the delocalized mixed-valence systems and is described by the new effective ZFS Hamiltonian H ZFS t . The ZFS Hamiltonian H ZFS t includes the operator of the Anderson–Hasegawa DE interaction and is active between the cluster states of different localizations, whereas the standard ZFS Hamiltonian, H ZFS 0 , acts in the localized states. The contributions of the anisotropic DE origin to the cluster ZFS parameters are linearly proportional to the DE parameters B0, Bμ and depend on the total spin S. The anisotropic DE contribution to the cluster ZFS parameter of the ground valence-delocalized state is of the same order of magnitude as the single-ion ZFS contributions." @default.
- W2014961111 created "2016-06-24" @default.
- W2014961111 creator A5038060085 @default.
- W2014961111 date "2006-08-01" @default.
- W2014961111 modified "2023-10-18" @default.
- W2014961111 title "Anisotropic double exchange in a valence-delocalized [Fe2.5+Fe2.5+] cluster. Spin–orbit coupling in the Anderson–Hasegawa double exchange model" @default.
- W2014961111 cites W1510913788 @default.
- W2014961111 cites W1511407547 @default.
- W2014961111 cites W1532692778 @default.
- W2014961111 cites W1580514967 @default.
- W2014961111 cites W1602639107 @default.
- W2014961111 cites W1965164724 @default.
- W2014961111 cites W1967632133 @default.
- W2014961111 cites W1970904934 @default.
- W2014961111 cites W1973752433 @default.
- W2014961111 cites W1975011125 @default.
- W2014961111 cites W1975165348 @default.
- W2014961111 cites W1979137502 @default.
- W2014961111 cites W1980185279 @default.
- W2014961111 cites W1980919883 @default.
- W2014961111 cites W1981915083 @default.
- W2014961111 cites W1984210284 @default.
- W2014961111 cites W1985957170 @default.
- W2014961111 cites W1986844239 @default.
- W2014961111 cites W1988376480 @default.
- W2014961111 cites W1988756299 @default.
- W2014961111 cites W1989742253 @default.
- W2014961111 cites W1991941342 @default.
- W2014961111 cites W1992111563 @default.
- W2014961111 cites W1995181804 @default.
- W2014961111 cites W2003296090 @default.
- W2014961111 cites W2003553733 @default.
- W2014961111 cites W2013835300 @default.
- W2014961111 cites W2017621202 @default.
- W2014961111 cites W2028704771 @default.
- W2014961111 cites W2030614491 @default.
- W2014961111 cites W2031729002 @default.
- W2014961111 cites W2033044813 @default.
- W2014961111 cites W2038203804 @default.
- W2014961111 cites W2039616951 @default.
- W2014961111 cites W2042733572 @default.
- W2014961111 cites W2046762431 @default.
- W2014961111 cites W2047610425 @default.
- W2014961111 cites W2049736058 @default.
- W2014961111 cites W2050342005 @default.
- W2014961111 cites W2053293457 @default.
- W2014961111 cites W2060124398 @default.
- W2014961111 cites W2065052815 @default.
- W2014961111 cites W2066173818 @default.
- W2014961111 cites W2069839767 @default.
- W2014961111 cites W2070449624 @default.
- W2014961111 cites W2071215777 @default.
- W2014961111 cites W2074411387 @default.
- W2014961111 cites W2080061204 @default.
- W2014961111 cites W2081310117 @default.
- W2014961111 cites W2087982431 @default.
- W2014961111 cites W2088081187 @default.
- W2014961111 cites W2090079874 @default.
- W2014961111 cites W2090384097 @default.
- W2014961111 cites W2094015083 @default.
- W2014961111 cites W2113571950 @default.
- W2014961111 cites W2168401996 @default.
- W2014961111 cites W2413212207 @default.
- W2014961111 cites W2497007159 @default.
- W2014961111 cites W2550838037 @default.
- W2014961111 cites W2950664137 @default.
- W2014961111 cites W2970511548 @default.
- W2014961111 doi "https://doi.org/10.1016/j.chemphys.2006.03.030" @default.
- W2014961111 hasPublicationYear "2006" @default.
- W2014961111 type Work @default.
- W2014961111 sameAs 2014961111 @default.
- W2014961111 citedByCount "1" @default.
- W2014961111 crossrefType "journal-article" @default.
- W2014961111 hasAuthorship W2014961111A5038060085 @default.
- W2014961111 hasConcept C121332964 @default.
- W2014961111 hasConcept C125020911 @default.
- W2014961111 hasConcept C127413603 @default.
- W2014961111 hasConcept C131584629 @default.
- W2014961111 hasConcept C159467904 @default.
- W2014961111 hasConcept C164866538 @default.
- W2014961111 hasConcept C168900304 @default.
- W2014961111 hasConcept C178790620 @default.
- W2014961111 hasConcept C184779094 @default.
- W2014961111 hasConcept C185592680 @default.
- W2014961111 hasConcept C199360897 @default.
- W2014961111 hasConcept C26873012 @default.
- W2014961111 hasConcept C41008148 @default.
- W2014961111 hasConcept C41999313 @default.
- W2014961111 hasConcept C62520636 @default.
- W2014961111 hasConcept C70050531 @default.
- W2014961111 hasConcept C78519656 @default.
- W2014961111 hasConcept C85725439 @default.
- W2014961111 hasConceptScore W2014961111C121332964 @default.
- W2014961111 hasConceptScore W2014961111C125020911 @default.
- W2014961111 hasConceptScore W2014961111C127413603 @default.
- W2014961111 hasConceptScore W2014961111C131584629 @default.
- W2014961111 hasConceptScore W2014961111C159467904 @default.
- W2014961111 hasConceptScore W2014961111C164866538 @default.