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- W2014962021 abstract "Treatment of the lithium β-diketiminate Li[{N(C 6 H 3 Pr 2 i -2,6)C(Me)} 2 CH] with an equivalent portion of arsenic(III) iodide unexpectedly afforded [Li(thf) 4 ] 2 [As 8 I 26 ] ( 1 ) in modest yield. Another new cluster anion featured in [Li(thf) 4 ] 2 [Li(thf) 6 ][As 7 I 24 ]·1.5(thf) ( 2 ) was obtained in excellent yield from lithium iodide and four equivalents of AsI 3 in thf. Using the same stoichiometry and solvent, but with SbI 3 in place of AsI 3 , furnished in good yield [Li(thf) 4 ] 4 [Sb 6 I 22 ]·2(thf) ( 3 ). The structures of the new crystalline orange ( 1 , 3 ) or orange/red ( 2 ) salts was established by single crystal X-ray diffraction. Each anion of 1 – 3 may be factorised into respectively [(AsI 2 ) 6 (AsI) 2 (μ 2 -I) 10 (μ 5 -I) 2 ] 2− ( 1 ), [{(AsI 2 )(μ 2 -I)(μ 3 -I)} 6 As] 3− ( 2 ) and [(SbI 3 ) 2 (SbI 2 ) 2 (SbI) 2 (μ 2 -I) 6 (μ 3 -I) 4 ] 4− ( 3 ). Each As atom in 2 and each Sb atom in 3 is the centre of a six-coordinate distorted octahedron, while the arsenic atoms in 1 have either four- or six-coordinate environments." @default.
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- W2014962021 date "2010-01-01" @default.
- W2014962021 modified "2023-09-26" @default.
- W2014962021 title "Synthesis and structures of lithium salts of two cluster iodoarsenate(III)s and a periodohexaantimonate(III)" @default.
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- W2014962021 doi "https://doi.org/10.1016/j.ica.2009.09.009" @default.
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