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• W2014965820 abstract "Abstract The phase behaviors, molecular conformations, and structural length scales of Y‐ (AB 2 ), H‐ (B 2 AB 2 ), and π ‐shaped [B(A)B(A)B] copolymers are compared using dissipative particle dynamics. Though their phase diagrams are similar, the stability of microstructures is enhanced with increasing complexity of molecular architecture (linear → Y → H or π ). In addition, the greater entropy loss associated with the disorder‐to‐order transition for H and π architectures makes it more difficult for them to undergo a microphase separation. When the H and π molecules pack to form an ordered structure, due to the significant presence of the chains in a bridge conformation, the structural length scales are strongly restricted. magnified image" @default.
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• W2014965820 date "2008-07-14" @default.
• W2014965820 modified "2023-09-27" @default.
• W2014965820 title "A Comparison of Y‐, H‐, and<i>π</i>‐shaped Diblock Copolymers via Dissipative Particle Dynamics" @default.
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• W2014965820 doi "https://doi.org/10.1002/mats.200700068" @default.
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