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• W2014967504 abstract "Raman scattering experiments of a single crystal of black phosphorus have been carried out at room temperature in a wide pressure range from 0.55 to 13 GPa in order to study a band overlapped metallization at 1.5 GPa and the structural phase transitions. Five Raman-active modes in the orthorhombic (A11) phase were detected as a function of pressure. The softening of the B1g and B3g1 modes was observed around 2 GPa. Above 4.7 GPa, these modes showed a sudden decrease in the intensity and two new broad bands appeared at 388 and 308 cm−1, corresponding to a transition to the rhombohedral (A7) phase. The broad bands which were assigned to the A1g and Eg modes of the A7 phase, exhibited remarkable softening with pressure. The A7 phase coexisted with the A11 phase up to 7 GPa. The transition to the simple cubic phase was also observed at 10.5 GPa with vanishment of the A1g mode." @default.
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• W2014967504 date "1997-11-01" @default.
• W2014967504 modified "2023-09-25" @default.
• W2014967504 title "Raman study of black phosphorus up to 13 GPa" @default.
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• W2014967504 doi "https://doi.org/10.1016/s0038-1098(97)00325-6" @default.
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